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refers to the suite of computational chemistry programs developed by Gaussian, Inc. The "09W" designation indicates Gaussian 09 for Windows (the "W" suffix denotes the Windows operating system version). Gaussian 09 is the successor to Gaussian 03 and was followed by Gaussian 16. The software provides advanced modeling capabilities for predicting molecular structures, reaction pathways, vibrational frequencies, thermochemical properties, NMR spectra, and much more.