If you can't access the console versions, many full playthroughs and let's plays are available on YouTube. While not the same as playing, you can still experience the story and see the combat system in action.
Alternative suggestion
Before downloading Captain America Super Soldier on PC, ensure your system meets the following requirements:
To get the game asset, you will need to find a trusted console ROM torrent site.
The game puts you in control of the ultimate Super-Soldier as you wield his legendary shield and engage in fluid acrobatic combat and platforming. You'll infiltrate a massive castle-turned-military-installation, battle the forces of Hydra, and face off against infamous enemies like the Red Skull, Arnim Zola, and Iron Cross.